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The rigid isomeric 5-(x-pyridyl)-1H-tetrazole ligands-directed various isopolymolybdate-based compounds: assembly, structures, and properties.
- Source :
-
Journal of Coordination Chemistry . Jan2016, Vol. 69 Issue 1, p1-11. 11p. 5 Diagrams, 1 Chart, 4 Graphs. - Publication Year :
- 2016
-
Abstract
- Two new isopolymolybdate-based metal–organic complexes, [Cu2(2-ptz)2(Mo4O14)0.5] (1) and [Cu3(OH)2(3-ptz)4(γ-H4Mo8O26)(H2O)4]·10H2O (2) (2-ptzH = 5-(2-pyridyl)-1H-tetrazole, 3-ptzH = 5-(3-pyridyl)-1H-tetrazole), constructed from isomeric ligands with different N-donor sites were synthesized under hydrothermal conditions. In1, each [Mo4O14]4−cluster connected with six neighboring [Mo4O14]4−clusters through six binuclear [Cu2(2-ptz)2]2+subunits to yield a 2-D layer. In2, bidentate inorganic [Mo8O26]4−anions link the trinuclear [Cu3(OH)2(3-ptz)4] clusters to construct a 1-D chain. Adjacent chains connect through Mo–N bonds between the [Mo8O26]4−anions and pyridyl groups from the trinuclear clusters to form a 2-D layer. The effect of the N-donor sites of the rigid isomeric ligands on the structures of1and2was discussed. The electrochemical properties and photocatalytic activities of1and2have also been studied. [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 69
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 112213322
- Full Text :
- https://doi.org/10.1080/00958972.2015.1118469