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High-performance xLi2MnO3·(1-x)LiMn1/3Co1/3Ni1/3O2 (0.1 ≤ x ≤0.5) as Cathode Material for Lithium-ion Battery.
- Source :
-
Electrochimica Acta . Jan2016, Vol. 188, p686-695. 10p. - Publication Year :
- 2016
-
Abstract
- Well-crystallized and high-performance x Li 2 MnO 3 ·(1- x )LiMn 1/3 Co 1/3 Ni 1/3 O 2 cathode materials over a wide compositional range (0.1 ≤ x ≤ 0.5) were prepared by a facile co-precipitation strategy. All samples show small and uniform particle dimensions in the range of 200-500 nm. 0.3Li 2 MnO 3 ·0.7LiMn 1/3 Co 1/3 Ni 1/3 O 2 (LMNC3) delivers the highest discharge capacities of 321.1 mA h g −1 at 0.1C, 305.2 mA h g −1 at 0.2 C, 243.2 mA h g −1 at 0.5C, 205.9 mA h g −1 at 1C, 182.1 mA h g −1 at 2C, and 133.7 mA h g −1 at 5C, respectively. LMNC3 also exhibits an excellent fast charge-discharge performance, and even at a charge-discharge rate of 2C in the 100th cycle its capacity still remains 128.2 mAh g −1 . The improved performance of LMNC3 can be ascribed to the improvement of electrochemical reversibility, lithium ion diffusion and ionic conductivity. First-principles calculation based on density function theory reveals that the strong covalent bonds formed between Mn-3d and O-2p orbits and stable Li 2 MnO 3 -enriched layer are helpful for stabilizing the LiMn 1/3 Co 1/3 Ni 1/3 O 2 structure. The same strategy adopted in this work could be helpful to develop other Li-rich cathodes with long cycle life and high rate performance. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 188
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 112677131
- Full Text :
- https://doi.org/10.1016/j.electacta.2015.12.036