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Extended π-Conjugated Dendrimers based on Truxene.

Authors :
Xiao-Yu Cao
Wen-Bin Zhang
Jin-Liang Wang
Xing-Hua Zhou
Hua Lu
Jian Pai, David R.
Source :
Journal of the American Chemical Society. 10/15/2003, Vol. 125 Issue 41, p12430-1231. 2p.
Publication Year :
2003

Abstract

Presents information on extended &b.pi;-conjugated dendrimers based on truxene. Preparation of a novel dendrimer containing up to nine truxene moieties with good yields; Difficulties in cyclotrimerizations due to steric hindrance of the giant truxene moiety; Affect of large torsion angle between the giant truxene moiety and the benzene ring on the full &b.pi;-delocalization of the whole molecule; Platform to synthesize a family of dendrimers utilizing giant polycyclic aromatics.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
41
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
11269771
Full Text :
https://doi.org/10.1021/ja037723d