Polyoxovanadate-based organic–inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cages.

Authors :: Zhang, Yu-Teng
Wang, Xin-Long
Zhou, En-Long
Wu, Xue-Song
Song, Bai-Qiao
Shao, Kui-Zhan
Su, Zhong-Min
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 3/7/2016, Vol. 45 Issue 9, p3698-3701. 4p.
Publication Year :: 2016
Abstract: Three polyoxovanadate-based metal–organic polyhedra (denoted as VMOP-1, -2, and -3), adopting isostructural discrete octahedral cage geometries, were successfully synthesized under solvothermal conditions. These structures are all built up from the same pentavanadate {V5O9Cl} cluster connected by linear bidentate ligands (H2L1 = H2BDC, H2L2 = H2BDC-NH2, H2L3 = H2BDC-Br), respectively. [ABSTRACT FROM AUTHOR]

Subjects :: *METAL-organic frameworks
*POLYOXOMETALATES
*VANADATES
*VANADIUM chlorides
*HYDROTHERMAL synthesis
*LIGANDS (Chemistry)
*X-ray powder diffraction

Language :: English
ISSN :: 14779226
Volume :: 45
Issue :: 9
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 113278298
Full Text :: https://doi.org/10.1039/c5dt04764a

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