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Mechanical, structural and thermal properties of Ag–Cu and ZnO reinforced polylactide nanocomposite films.
- Source :
-
International Journal of Biological Macromolecules . May2016, Vol. 86, p885-892. 8p. - Publication Year :
- 2016
-
Abstract
- Plasticized polylactic acid (PLA) based nanocomposite films were prepared by incorporating polyethylene glycol (PEG) and two selected nanoparticles (NPs) [silver–copper (Ag–Cu) alloy (<100 nm) and zinc oxide (ZnO) (<50 and <100 nm)] through solvent casting method. Incorporation of Ag–Cu alloy into the PLA/PEG matrix increased the glass transition temperature ( T g ) significantly. The crystallinity of the nanocomposites (NCs) was significantly influenced by NP incorporation as evidenced from differential scanning calorimetry (DSC) and X-ray diffraction (XRD) analysis. The PLA nanocomposite reinforced with NPs exhibited much higher tensile strength than that of PLA/PEG blend. Melt rheology of NCs exhibited a shear-thinning behavior. The mechanical property drastically reduced with a loading of NPs, which is associated with degradation of PLA. SEM micrographs exhibited that both Ag–Cu alloy and ZnO NPs were dispersed well in the PLA film matrix. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01418130
- Volume :
- 86
- Database :
- Academic Search Index
- Journal :
- International Journal of Biological Macromolecules
- Publication Type :
- Academic Journal
- Accession number :
- 113950806
- Full Text :
- https://doi.org/10.1016/j.ijbiomac.2016.02.034