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4(N,N-dimethylamino) benzaldehyde nicotinic hydrazone as corrosion inhibitor for mild steel in 1 M HCl solution: An experimental and theoretical study.

Authors :
Singh, Dharmendra Kumar
Kumar, Santosh
Udayabhanu, G.
John, Rohith P.
Source :
Journal of Molecular Liquids. Apr2016, Vol. 216, p738-746. 9p.
Publication Year :
2016

Abstract

4(N,N-dimethylamino) benzaldehyde nicotinic acid hydrazone is prepared and investigated as corrosion inhibitor for mild steel in 1 M HCl using weight loss, electrochemical method, quantum chemical calculation, FE-SEM and AFM method. The inhibition efficiency increases with increasing inhibitor concentration. The polarisation study indicates that it acts as a mixed type corrosion inhibitor. The adsorption of inhibitor is spontaneous and obeys the Langmuir's adsorption isotherm. The FE-SEM images and AFM images of mild steel support strong adsorption and high inhibition efficiency of the inhibitor. Quantum chemical parameters are also in agreement with experimental obtained efficiency. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
01677322
Volume :
216
Database :
Academic Search Index
Journal :
Journal of Molecular Liquids
Publication Type :
Academic Journal
Accession number :
113951028
Full Text :
https://doi.org/10.1016/j.molliq.2016.02.012