Back to Search
Start Over
Interactions of a water-soluble calix[4]arene with spermine: solution and solid-state characterisation.
- Source :
-
Supramolecular Chemistry . May/Jun2016, Vol. 28 Issue 5/6, p499-505. 7p. - Publication Year :
- 2016
-
Abstract
- The octaanionic 5,11,17,23-tetrasulfonato-25,26,27,28-tetrakis(hydroxycarbonylmethoxy)-calix[4]arene (cone conformation) (C4TsTc) was investigated as a sensor for the biogenic tetracationic polyamine, spermine.(H4Spe4+). Fluorescence titration experiments of the water-soluble calixarene with spermine showed the formation of the 2:1 and 1:1 calixarene:spermine complexes in solution. The single crystal X-ray diffraction analysis of [(NaC4TsTc)4·(H4Spe)7] confirmed the formation of 2:1 and 1:1 calixarene:spermine species and showed that the water-soluble calixarene binds the spermine either by partially hosting it in the inner cavity or through the carboxylate groups on the lower rim. In order to investigate the effect of multivalent systems, supramolecular assemblies of octaanionic calixarene molecules templated bymeso-tetrakis(4-N-methylpyridyl)porphyrin (H2T4) in different stoichiometric porphyrin:calixarene ratios (1:4 and 3:4) were also tested for spermine binding in solution. Fluorescence titration experiments with the 1:4 and 3:4 H2T4:C4TsTc supramolecular complexes showed that the multivalent assemblies are more sensitive to the presence of spermine than the calixarene alone. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SPERMINE
*POLYAMINES
*BIOGENIC amines
*NATURAL resources
*CALIXARENES
Subjects
Details
- Language :
- English
- ISSN :
- 10610278
- Volume :
- 28
- Issue :
- 5/6
- Database :
- Academic Search Index
- Journal :
- Supramolecular Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 114245769
- Full Text :
- https://doi.org/10.1080/10610278.2015.1125900