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Boron-Catalyzed Aromatic C–H Bond Silylation with Hydrosilanes.
- Source :
-
Journal of the American Chemical Society . 3/23/2016, Vol. 138 Issue 11, p3663-3666. 4p. - Publication Year :
- 2016
-
Abstract
- Metal-free catalytic C–H silylation of a series of aromatic compounds such as N,N-disubstituted anilines with various hydrosilanes has been achieved for the first time using commercially available B(C6F5)3 as a catalyst. This protocol features simple and neutral reaction conditions, high regioselectivity, wide substrate scope (up to 40 examples), Si–Cl bond compatibility, and no requirement for a hydrogen acceptor. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 138
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 114320425
- Full Text :
- https://doi.org/10.1021/jacs.6b01349