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Palladium-catalyzed silylation reaction between benzylic halides and silylboronate.
- Source :
-
Chemical Communications . 4/25/2016, Vol. 52 Issue 32, p5609-5612. 4p. - Publication Year :
- 2016
-
Abstract
- An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BENZYLIC group
*STEREOSPECIFICITY
*HALIDES
*SILANE compounds
*BORONIC esters
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 32
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 114495735
- Full Text :
- https://doi.org/10.1039/c6cc00713a