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Protonation of carbene-stabilized diphosphorus: complexation of HP2+.
- Source :
-
Chemical Communications . 4/28/2016, Vol. 52 Issue 33, p5746-5748. 3p. - Publication Year :
- 2016
-
Abstract
- Reaction of carbene-stabilized diphosphorus, L:P–P:L (5) (L: = :C{N(2,6-Pri2C6H3)CH}2) with pyridine hydrochloride yields [L:(H)P–P:L]Cl (6), a salt containing the HP2+ cation―the elusive phosphorus analogue of the well known diazonium cation, HN2+. In addition to reporting the synthesis and structure, the nature of (6) was further probed by DFT computations. Interestingly, carbenes may be employed to deprotonate (6), affording the starting material (5). [ABSTRACT FROM AUTHOR]
- Subjects :
- *CARBENES
*PYRIDINE
*PHOSPHORUS
*DIAZONIUM compounds
*CATIONS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 33
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 114542564
- Full Text :
- https://doi.org/10.1039/c6cc01759b