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Tetra-Antimony(III)-Bridged 18-Tungsto-2-Arsenates(V), [(LSbIII)4(A-α-AsVW9O34)2]10- (L = Ph, OH): Turning Bioactivity On and Off by Ligand Substitution.
- Source :
-
Inorganic Chemistry . 4/18/2016, Vol. 55 Issue 8, p3718-3720. 3p. - Publication Year :
- 2016
-
Abstract
- Two tetra-antimony(III)-bridged, sandwich-type 18-tungsto-2-arsenates(V), [(LSbIII)4(A-α-AsVW9O34)2]10- (L = Ph (1), OH (2)), were prepared and fully characterized in the solid state and in solution. Both polyanions are stable in aqueous physiological medium for at least 24 h (at concentrations &#8805=;2.5 × 10-6 M). Despite the presence of an isostructural tetra-antimony(III) motif in 1 and 2, distinctly different antibacterial activity was observed for both polyanions. The minimum inhibitory concentrations (MIC) of 1 (7.8-62.5 μg/mL) is lower than for any other organoantimony(III)-containing polyoxometalate reported to date. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 55
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 114781699
- Full Text :
- https://doi.org/10.1021/acs.inorgchem.6b00107