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Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents.
- Source :
-
Angewandte Chemie . 4/25/2016, Vol. 128 Issue 18, p5640-5644. 5p. - Publication Year :
- 2016
-
Abstract
- In the presence of a nickel catalyst, 1,3-butadiene undergoes selective dimerization and alkylarylation with alkyl fluorides and aryl Grignard reagents to give 1,6-octadienes with alkyl and aryl groups at the 3- and 8-positions, respectively, by the consecutive formation of three carbon-carbon bonds. The formation of an anionic nickel complex plays an important role in forming C−C bonds with alkyl fluorides. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NICKEL catalysts
*DIMERIZATION
*ALKYL fluorides
*ARYL group
*CARBON-carbon bonds
Subjects
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 128
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 114818505
- Full Text :
- https://doi.org/10.1002/ange.201601126