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Fabrication of bimodal-pore SrTiO3 microspheres with excellent photocatalytic performance for Cr(VI) reduction under simulated sunlight.
- Source :
-
Journal of Hazardous Materials . Jul2016, Vol. 312, p45-54. 10p. - Publication Year :
- 2016
-
Abstract
- Solving the increasing contamination from toxic heavy metal ions in wastewater is an imperative issue in photocatalysis research area. In this study, three-dimensional (3D) porous SrTiO 3 microspheres have been fabricated by a sol–gel-templating method using the agarose gel bead containing SrCO 3 granules as the template. The resultant SrTiO 3 microspheres, several tens of micrometers in diameter, exhibit a bimodal pore structure, in which the macropore about 70–150 nm in size stems from SrCO 3 granules and the mesopore about 3 nm is formed via removing the agarose fiber embedded in the composite microspheres. The porous framework of SrTiO 3 microspheres is assembled by regular single-crystalline SrTiO 3 nanocubes with an edge length of 100 ± 10 nm. The highly interconnected porous network renders numerous pathways for the rapid mass transport, strong adsorption of reactants and multi-reflection of incident light. Moreover, the as-prepared SrTiO 3 microspheres exhibit excellent photocatalytic performance for the Cr(VI) reduction under simulated sunlight, which can reduce nearly 100% Cr(VI) at pH 2 within 2 h and retain a relatively high reduction ability after six recycles. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03043894
- Volume :
- 312
- Database :
- Academic Search Index
- Journal :
- Journal of Hazardous Materials
- Publication Type :
- Academic Journal
- Accession number :
- 114873879
- Full Text :
- https://doi.org/10.1016/j.jhazmat.2016.03.032