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Synthesis of Lithium Boracarbonate Ion Pairs by Copper-Catalyzed Multi-Component Coupling of Carbon Dioxide, Diboron, and Aldehydes.
- Source :
-
Angewandte Chemie . 5/17/2016, Vol. 128 Issue 21, p6365-6368. 4p. - Publication Year :
- 2016
-
Abstract
- The catalytic selective multi-component coupling of CO2, bis(pinacolato)diboron, LiOtBu, and a wide range of aldehydes has been achieved for the first time by using an NHC-copper catalyst. This transformation has efficiently afforded a series of novel lithium cyclic boracarbonate ion pair compounds in high yields from readily available starting materials. This protocol has not only provided a new catalytic process for the utilization of CO2, but it has also constituted a novel route for the efficient synthesis of a new class of lithium borate compounds that might be of interest as potential electrolyte candidates for lithium ion batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 128
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 115296263
- Full Text :
- https://doi.org/10.1002/ange.201602278