ChemInform Abstract: Efficient Synthesis of Chiral Trisubstituted 1,2-Allenyl Ketones by Catalytic Asymmetric Conjugate Addition of Malonic Esters to Enynes.

Authors :: Yao, Qian
Liao, Yuting
Lin, Lili
Lin, Xiaobin
Ji, Jie
Liu, Xiaohua
Feng, Xiaoming
Source :: ChemInform. May2016, Vol. 47 Issue 22, pno-no. 1p.
Publication Year :: 2016
Abstract: The conjugate addition of malonic esters to enynes in the presence of a scandium(III)/N,N-dioxide complex yields a range of trisubstituted allenyl ketones with good diastereomeric ratios and excellent e.e.-values. [ABSTRACT FROM AUTHOR]

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