Ferrocenyl-penta-(β-naphthyl)benzene — Synthesis, structure, and dynamic behaviour.

3-Ferrocenyl-2,4,5-tri-(β-naphthyl)cyclopentadienone undergoes a Diels–Alder reaction with di-(β-naphthyl) acetylene to yield, after elimination of carbon monoxide, ferrocenyl-penta-(β-naphthyl)benzene (4). 1H and 13C variable-temperature NMR studies on 4 reveal the existence of multiple diastereoisomers at low temperature. These data are interpreted in terms of slowed rotation of the naphthyl groups, and are supported by the X-ray crystal structure of 4, which exhibits disorder at three of the naphthyl sites. [ABSTRACT FROM AUTHOR]