Ag(I)-Catalyzed Three-Component Reaction of 2-Alkynylbenzaldehydes, Amines, and Diazo Compounds.

Authors :: Xiao, Tiebo
Peng, Pai
Xie, Yang
Wang, Zhao‐yang
Zhou, Lei
Source :: ChemInform. 1/7/2016, Vol. 47 Issue 4, p141-no. 2p.
Publication Year :: 2016
Abstract: A one-pot three-component cyclization of diazo compounds as nucleophiles with primary aromatic amines and alkynylbenzaldehydes gives 3-benzazepines via a cascade imine--yne cyclization/nucleophilic addition/1,2-aryl migrations. Diazo dihydroisoquinolines are obtained under slightly modified conditions. [ABSTRACT FROM AUTHOR]

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