Back to Search
Start Over
Transformation pathways of 2,4,6-trinitrobenzoic acid in the aqueous-phase hydrogenation over Pd/C catalyst.
- Source :
-
Journal of Molecular Catalysis A: Chemistry . Aug2016, Vol. 420, p190-199. 10p. - Publication Year :
- 2016
-
Abstract
- Results of the catalytic hydrogenation of 2,4,6-trinitrobenzoic acid (TNBA) in the presence of 1% Pd/C catalyst with analysis of the reaction products at the steps corresponding to the consumption of 1, 3, 5, 6, 8 and 9 mols of hydrogen per mol of TNBA are presented. Numerous reaction intermediates were identified using the 1 H and 13 C NMR spectroscopy; the reaction mixture composition was assessed quantitatively at different steps of the hydrogenation. The data obtained were used to propose a scheme of TNBA transformations over the Pd/C catalyst in the aqueous-phase reaction conditions. The data on the component composition at different steps of TNBA hydrogenation are important to understand the process chemistry, to explore the possibility of selective formation of different types of intermediate nitroamino compounds, and to synthesize high-performance catalysts for the hydrogenation of aromatic polynitro compounds. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13811169
- Volume :
- 420
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Catalysis A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 115798592
- Full Text :
- https://doi.org/10.1016/j.molcata.2016.04.014