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Thermal Responsive Ion Selectivity of Uranyl Peroxide Nanocages: An Inorganic Mimic of K+ Ion Channels.
- Source :
-
Angewandte Chemie International Edition . 6/6/2016, Vol. 55 Issue 24, p6887-6891. 5p. - Publication Year :
- 2016
-
Abstract
- An actinyl peroxide cage cluster, Li48+ mK12(OH) m[UO2(O2)(OH)]60 (H2O) n ( m≈20 and n≈310; U60), discriminates precisely between Na+ and K+ ions when heated to certain temperatures, a most essential feature for K+ selective filters. The U60 clusters demonstrate several other features in common with K+ ion channels, including passive transport of K+ ions, a high flux rate, and the dehydration of U60 and K+ ions. These qualities make U60 (a pure inorganic cluster) a promising ion channel mimic in an aqueous environment. Laser light scattering (LLS) and isothermal titration calorimetry (ITC) studies revealed that the tailorable ion selectivity of U60 clusters is a result of the thermal responsiveness of the U60 hydration shells. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 55
- Issue :
- 24
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 115813468
- Full Text :
- https://doi.org/10.1002/anie.201601852