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Robust and stable ruthenium alloy electrocatalysts for hydrogen evolution by seawater splitting.

Authors :
Niu, Xiaoman
Tang, Qunwei
He, Benlin
Yang, Peizhi
Source :
Electrochimica Acta. Aug2016, Vol. 208, p180-187. 8p.
Publication Year :
2016

Abstract

Seawater splitting by complicated electrocatalytic processes is promising for hydrogen evolution. Here we present a series of robust electrodes by electrodepositing RuCo and RuCoMo x alloys on Ti foil substrates for hydrogen evolution from seawater splitting. The preliminary results demonstrate that Ti foil supported RuCo and RuCoMo x alloy electrodes require overpotentials of ∼387 and ∼550 mV to drive the hydrogen evolution reaction (HER) at a benchmark current density of 10 mA cm −2 , respectively. Moreover, the resultant Ti foil supported RuCoMo x electrode shows excellent stability under persistent operation at a constant current density of −1.2 V over 12 h. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00134686
Volume :
208
Database :
Academic Search Index
Journal :
Electrochimica Acta
Publication Type :
Academic Journal
Accession number :
115978752
Full Text :
https://doi.org/10.1016/j.electacta.2016.04.184