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Highly enantioselective Michael addition of α,α-disubstituted aldehydes to nitroolefins.
- Source :
-
Research on Chemical Intermediates . Jul2016, Vol. 42 Issue 7, p6373-6380. 8p. 1 Diagram, 4 Charts. - Publication Year :
- 2016
-
Abstract
- A highly enantioselective Michael addition reaction of α,α-disubstituted aldehydes to β-nitrostyrenes has been developed. In the presence of rosin-based chiral primary amine-thiourea, γ-nitroaldehydes were afforded in excellent enantioselectivities (up to 99 % ee) with up to 99 % yield. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09226168
- Volume :
- 42
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Research on Chemical Intermediates
- Publication Type :
- Academic Journal
- Accession number :
- 116100619
- Full Text :
- https://doi.org/10.1007/s11164-016-2468-0