ChemInform Abstract: Unique Steric Effect of Geminal Bis(silane) to Control the High exo-Selectivity in Intermolecular Diels-Alder Reaction.

Authors :: Liu, Zengjin
Lin, Xinglong
Yang, Na
Su, Zhishan
Hu, Changwei
Xiao, Peihong
He, Yanyang
Song, Zhenlei
Source :: ChemInform. Jul2016, Vol. 47 Issue 30, pno-no. 1p.
Publication Year :: 2016
Abstract: Due to the unique steric effect of di(silyl)methyl (DSM) groups, an exo-selective intermolecular Diels-Alder reaction of geminal bis(silyl) dienes with α,β-unsaturated carbonyl compounds is achieved. [ABSTRACT FROM AUTHOR]

Subjects :: *DIOLEFINS
*STERIC factor (Chemistry)
*SILANE compounds
*DIELS-Alder reaction
*CARBONYL compounds

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