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A carbon-free polyoxometalate molecular catalyst with a cobalt–arsenic core for visible light-driven water oxidation.
- Source :
-
Chemical Communications . 8/7/2016, Vol. 52 Issue 61, p9514-9517. 4p. - Publication Year :
- 2016
-
Abstract
- A carbon-free, stable, homogeneous water oxidation catalyst based on the unique hepta-nuclear cobalt–arsenic core (“fused” double-quasi-cubane) and polyoxometalate ligands, Na12[{CoII7AsIII6O9(OH)6}(A-α-SiW9O34)2]·8H2O (1), was synthesized, thoroughly characterized and employed to catalyze water oxidation under visible-light-driven conditions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *OXIDATION
*POLYOXOMETALATES
*CATALYSIS
*CHEMICAL synthesis
*WATER
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 61
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 116945640
- Full Text :
- https://doi.org/10.1039/c6cc03763a