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Anderson-like alkoxo-polyoxovanadate clusters serving as unprecedented second building units to construct metal–organic polyhedra.
- Source :
-
Chemical Communications . 8/11/2016, Vol. 52 Issue 62, p9632-9635. 4p. - Publication Year :
- 2016
-
Abstract
- Unprecedented Anderson-like alkoxo-polyoxovanadate [V6O6(OCH3)9(μ6-SO4)(COO)3]2− polyanions can serve as 3-connected second building units (SBUs) that assemble with dicarboxylate or tricarboxylate ligands to form a new family of metal organic tetrahedrons of V4E6 and V4F4 type (V = vertex, E = edge, and F = face). To our knowledge, this alkoxo-polyoxovanadate-based SBU is the first ever reported. [ABSTRACT FROM AUTHOR]
- Subjects :
- *POLYANIONS
*LIGANDS (Chemistry)
*TETRAHEDRA
*CARBOXYLATES
*CARBOXYLIC acids
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 62
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 117002923
- Full Text :
- https://doi.org/10.1039/c6cc04583a