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A Novel Self-assembled Nickel(II)-Cerium(III) Heterotetranuclear Dimer Constructed from N2O2-type Bisoxime and Terephthalic Acid: Synthesis, Structure, and Photophysical Properties.
- Source :
-
Zeitschrift für Anorganische und Allgemeine Chemie . Jul2016, Vol. 642 Issue 15, p834-839. 6p. - Publication Year :
- 2016
-
Abstract
- By self-assembly of a Salamo-type ligand H2L [H2L = 1,2-bis(3-methoxysalicylideneaminooxy)ethane] with Ni(OAc)2·4H2O, Ce(NO3)3·6H2O, and H2bdc (H2bdc = terephthalic acid), a novel NiII-CeIII heterometallic complex, [{Ni(L)Ce(NO3)2(CH3OH) (DMF)}2(bdc)], was obtained. Two crystallographically equivalent [Ni(L)Ce(NO3)2(CH3OH)(DMF)] moieties lie in the inversion center, and are linked by one bdc2- ligand leading to a heterotetranuclear dimer, in which the carboxylato group bridges the NiII and CeIII atoms. Moreover, the photophysical properties of the NiII-CeIII complex were studied. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NICKEL
*CERIUM
*TEREPHTHALIC acid
*CHEMICAL synthesis
*DIMERS
Subjects
Details
- Language :
- English
- ISSN :
- 00442313
- Volume :
- 642
- Issue :
- 15
- Database :
- Academic Search Index
- Journal :
- Zeitschrift für Anorganische und Allgemeine Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 117071045
- Full Text :
- https://doi.org/10.1002/zaac.201600125