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A practical enantioselective synthesis of massoialactone via hydrolytic kinetic resolution
- Source :
-
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry . Jan2004, Vol. 45 Issue 4, p849. 3p. - Publication Year :
- 2004
-
Abstract
- An efficient enantioselective synthesis of (R)- and (S)-massoialactone has been achieved. The key steps are the hydrolytic kinetic resolution of a racemic epoxyheptane with (R,R)-(salen)–CoIIIOAc complex and ring-closing metathesis of homoallylic alcohol derived acrylate esters using Grubb’s catalyst. [Copyright &y& Elsevier]
- Subjects :
- *CYCLOPOLYMERIZATION
*METATHESIS reactions
*ALCOHOL
Subjects
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 45
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 11729546
- Full Text :
- https://doi.org/10.1016/j.tetlet.2003.11.032