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A Pb -based coordination polymer with 5-(1H-tetrazol-5-yl)isophthalic acid ligand: structure and photoluminescence.
- Source :
-
Journal of Coordination Chemistry . Sep2016, Vol. 69 Issue 17, p2573-2579. 7p. - Publication Year :
- 2016
-
Abstract
- A coordination polymer, [Pb2(OH)(tzia)]·2H2O (1), has been prepared by solvothermal reaction of 5-(1H-tetrazol-5-yl)isophthalic acid (H3tzia) and Pb(NO3)2. The polymer1is based on an unprecedented centrosymmetric tetranuclear [Pb4(OH)2(COO)4(ttaz)2] cluster linked by a multidentate tzia ligand, affording a 2-D 3,6-connectedkgdlayer. The adjacent layers are further jointed by Pb⋯O interactions to form a 3-D supramolecular framework with a rare (3,8)-connectedtfz-d; UO3topology. Photoluminescent properties of H3tzia,1, and1-desolvated have been further investigated, and it was interesting to find that1-desolvated due to the removal of lattice water molecules reveals stronger photoluminescence than1. [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 69
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 117420911
- Full Text :
- https://doi.org/10.1080/00958972.2016.1215441