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AIE-active tetraphenylethene functionalized metal–organic framework for selective detection of nitroaromatic explosives and organic photocatalysis.
- Source :
-
Chemical Communications . 9/28/2016, Vol. 52 Issue 75, p11284-11287. 4p. - Publication Year :
- 2016
-
Abstract
- AIE-active luminogen tetraphenylethene (TPE) was incorporated into a UiO-isoreticular zirconium metal–organic framework via the strategy of mixed dicarboxylate struts, and the resulting functionalized MOF shows a strong blue-green emission and selective sensing of nitroaromatic explosives 2,4,6-trinitrophenol (TNP) and 2,4-dinitrophenol (DNP) through fluorescence quenching. Moreover, the luminescent MOF exhibits efficient photocatalytic activity for aerobic cross-dehydrogenative coupling reactions mediated by visible light. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 75
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 118067278
- Full Text :
- https://doi.org/10.1039/c6cc04997d