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Zn/Fe-MOFs-derived hierarchical ball-in-ball ZnO/ZnFe2O4@carbon nanospheres with exceptional lithium storage performance.
- Source :
-
Journal of Alloys & Compounds . Dec2016 Part A, Vol. 688, p211-218. 8p. - Publication Year :
- 2016
-
Abstract
- Transition metal oxides@carbon(C) nanocomposites with hierarchical three-dimensional (3D) core-shell nanoarchitectures, large surface area and high electrical conductivity as anode materials for lithium ion batteries (LIBs) are very desirable. Herein, we developed a simple and feasible route to fabricate novel hierarchical 3D ball-in-ball ZnO/ZnFe 2 O 4 @C nanospheres with well-defined hollow microstructures via one-step carbonization of Zn/Fe-metal organic frameworks for the first time. The as-prepared hierarchical 3D ball-in-ball ZnO/ZnFe 2 O 4 @C nanospheres were carefully characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, X-ray powder diffraction, thermogravimetric analysis, N 2 adsorption/desorption isotherm, transmission electron microscopy and electrochemical techniques. The results showed ultrafine ZnO and ZnFe 2 O 4 nanocrystals were uniformly encapsulated by few carbon layers which was derived from in-situ carbonization of the organic ligands. Benefiting from their special hollow nanoarchitectures, ultrafine ZnO and ZnFe 2 O 4 nanocrystals encapsulated by a few carbon layers, large specific surface area and high electrical conductivity, the hierarchical 3D ball-in-ball ZnO/ZnFe 2 O 4 @C nanospheres presented high reversible capacities of 1283 and 1100 mA h g −1 after first 100 cycles and the following 100 cycles at current density of 100 and 200 mA g −1 , respectively. A high specific capacity of 155 mA h g −1 was obtained at relatively large current rates of 20 A g −1 . [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 688
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 118178881
- Full Text :
- https://doi.org/10.1016/j.jallcom.2016.07.011