Efficient gas barrier properties of multi-layer films based on poly(lactic acid) and fish gelatin.

Multi-layer film structures of poly(lactic acid) (PLA) and fish gelatin (FG), prepared using the solvent casting technique, were studied in an effort to produce bio-based films with low oxygen (OP) and water vapor permeability (WVP). The scanning electron microscopy (SEM) images of triple-layer film showed that the outer PLA layers are being closely attached to the inner FG layer to make continuous film. The OP of multi-layer film (5.02 cm 3 /m 2 day bar) decreased more than 8-fold compared with that of the PLA film, and the WVP of multi-layer film (0.125 g mm/ kPa h m 2 ) also decreased 11-fold compared with that of the FG film. Lamination with PLA profoundly increased the water resistance of the bare gelatin film. Meanwhile, the tensile strength of the triple-layer film (25 ± 2.13 MPa) was greater than that of FG film (7.48 ± 1.70 MPa). At the same time, the resulting film maintains high optical clarity. Differential scanning calorimetry (DSC) analysis also revealed that the materials were compatible showing only one T g which decreased with FG deposition. This material exhibits an environmental-friendliness potential and a high versatility in food packaging. [ABSTRACT FROM AUTHOR]