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Palladium-Catalyzed Ylidyl-Carbonylation of Aryl Halides To Produce α-Acylphosphoranes.
- Source :
-
Organic Letters . Oct2016, Vol. 18 Issue 19, p4824-4827. 4p. - Publication Year :
- 2016
-
Abstract
- An efficient synthesis of α-acylphosphoranes by palladium-catalyzed carbonylation of aryl iodides with carbon monoxide and stabilized phosphonium ylides has been developed. Featuring 44 examples, the protocol displayed a wide substrate scope under mild reaction conditions, showcasing its potential in synthetic organic chemistry. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PHOSPHORANE
*PALLADIUM catalysts
*CARBONYLATION
*IODIDES
*ARYL halides
Subjects
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 18
- Issue :
- 19
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 118665590
- Full Text :
- https://doi.org/10.1021/acs.orglett.6b02278