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A chromone-derived Schiff-base as Al3+ “turn-on” fluorescent probe based on photoinduced electron-transfer (PET) and C[dbnd]N isomerization.
- Source :
-
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry . Nov2016, Vol. 57 Issue 44, p4898-4904. 7p. - Publication Year :
- 2016
-
Abstract
- In this study, a novel chromone-derived Schiff-base ligand which was called bis(6-hydroxychromone-3-methylidene)- o -phenylenediimine ( 1 ) was designed, synthesized, and evaluated as an Al 3+ “turn on” fluorescent probe. This probe 1 showed good selectivity and high sensitivity towards Al 3+ in the presence of most metal ions, and a remarkable enhancement by about 30.91-fold in fluorescence emission intensity at 459 nm was observed with addition of 1 equiv of Al 3+ , which was attributed to the inhibition of photoinduced electron-transfer (PET) phenomenon and C N isomerization process at the excited state. Moreover, the fluorescence response of 1 to Al 3+ was nearly completed within 10 min. Thus, this probe 1 could be utilized for sensing and monitoring Al 3+ in environmental and biological systems for real-time detection. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 57
- Issue :
- 44
- Database :
- Academic Search Index
- Journal :
- Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 118696415
- Full Text :
- https://doi.org/10.1016/j.tetlet.2016.09.058