Cu2O-loaded gas diffusion electrodes for the continuous electrochemical reduction of CO2 to methanol.

Gas-diffusion electrodes are prepared with commercial Cu 2 O and Cu 2 O–ZnO mixtures deposited onto carbon papers and evaluated for the continuous CO 2 gas phase electroreduction in a filter-press electrochemical cell. The process mainly produced methanol, as well as small quantities of ethanol and n -propanol. The analysis includes the evaluation of key variables with effect in the electroreduction process: current density ( j = 10–40 mA cm −2 ), electrolyte flow/area ratio ( Q e / A = 1–3 ml min −1 cm −2 ) and CO 2 gas flow/area ratio ( Q g / A = 10–40 ml min −1 cm −2 ), using a 0.5 M KHCO 3 aqueous solution. The maximum CO 2 conversion efficiency to liquid-phase products was 54.8% and 31.4% for Cu 2 O and Cu 2 O/ZnO-based electrodes at an applied potential of −1.39 and −1.16 V vs. Ag/AgCl, respectively. Besides, the Cu 2 O/ZnO electrodes are expected to catalyze the CO 2 electroreduction for over 20 h. These results may provide new insights into the application of gas diffusion electrodes to alleviate mass transfer limitations in electrochemical systems for the transformation of CO 2 to alcohols. [ABSTRACT FROM AUTHOR]