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Sodium 1,1′-dinitramino-5,5′-bistetrazolate: A 3D metal-organic framework as green energetic material with good performance and thermo stability.
- Source :
-
Inorganica Chimica Acta . Jan2017 Part 1, Vol. 455, p152-157. 6p. - Publication Year :
- 2017
-
Abstract
- A reticular 3D energetic metal-organic framework, sodium 1,1′-dinitramino-5,5′-bistetrazolate was first synthesized and fully characterized by crystal X-ray diffraction, elemental analysis, mass spectrometry, IR spectroscopy, differential scanning calorimetry (DSC) and sensitivity test. It shows a density of 1.892 g·cm −3 , a positive oxygen balance and a high decomposition temperature of 250 °C. The promising energetic properties were also investigated by using theoretical calculation methods. Its calculated heat of formation (529.5 kJ·mol −1 ) combined with impressive heat of detonation (5080 kJ·kg −1 ), good thermal stabilities and clean detonation products make it a competitive replacement as a green energetic material. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201693
- Volume :
- 455
- Database :
- Academic Search Index
- Journal :
- Inorganica Chimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 119651708
- Full Text :
- https://doi.org/10.1016/j.ica.2016.10.031