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ChemInform Abstract: Cooperative N-Heterocyclic Carbene/Palladium-Catalyzed Enantioselective Umpolung Annulations.

Authors :
Guo, Chang
Fleige, Mirco
Janssen‐Mueller, Daniel
Daniliuc, Constantin G.
Glorius, Frank
Source :
ChemInform. Nov2016, Vol. 47 Issue 50, pno-no. 1p.
Publication Year :
2016

Abstract

The regioselective title reaction between vinyl benzoxazinanones and aryl, alkenyl or alkyl substituted enals delivers benzazepine derivatives in high yields, with high diastereo- and excellent enantioselectivities. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*HETEROCYCLIC compound derivatives
*CARBENES
*PALLADIUM catalysts
*ENANTIOSELECTIVE catalysis
*ANNULATION
*REGIOSELECTIVITY (Chemistry)

Details

Language :
English
ISSN :
09317597
Volume :
47
Issue :
50
Database :
Academic Search Index
Journal :
ChemInform
Publication Type :
Academic Journal
Accession number :
119752663
Full Text :
https://doi.org/10.1002/chin.201650153
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