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Direct construction of xanthene and benzophenone derivatives via Brønsted acid controlled Diels-Alder reaction of 3-vinylchromones and arynes.

Authors :
Huang, Xu-Jiao
Tao, Yuan
Li, Yue-Kun
Wu, Xin-Yan
Sha, Feng
Source :
Tetrahedron. Dec2016, Vol. 72 Issue 52, p8565-8577. 13p.
Publication Year :
2016

Abstract

A Brønsted acid controlled Diels-Alder reaction of 3-vinylchromones with arynes has been developed. By employing different kinds and amounts of acid, 9-aryl-9 H -xanthen-9-ols or ortho -hydroxybenzophenones could be controllably furnished in good yields in an atom- and step-economic manner. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00404020
Volume :
72
Issue :
52
Database :
Academic Search Index
Journal :
Tetrahedron
Publication Type :
Academic Journal
Accession number :
119846235
Full Text :
https://doi.org/10.1016/j.tet.2016.11.028