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PhSO2SCF2H: A Shelf-Stable, Easily Scalable Reagent for Radical Difluoromethylthiolation.
- Source :
-
Angewandte Chemie International Edition . 12/19/2016, Vol. 55 Issue 51, p15807-15811. 5p. - Publication Year :
- 2016
-
Abstract
- A new shelf-stable and easily scalable difluoromethylthiolating reagent S-(difluoromethyl) benzenesulfonothioate (PhSO2SCF2H) was developed. PhSO2SCF2H is a powerful reagent for radical difluoromethylthiolation of aryl and alkyl boronic acids, decarboxylative difluoromethylthiolation of aliphatic acids, and a phenylsulfonyl-difluoromethylthio difunctionalization of alkenes under mild reaction conditions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CHEMICAL reagents
*ARYL group
*ALKYL compounds
*CHEMICAL reactions
*BORONIC acids
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 55
- Issue :
- 51
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 120155576
- Full Text :
- https://doi.org/10.1002/anie.201609468