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(+)-Camphor-mediated kinetic resolution of allylalanes: a strategy towards enantio-enriched cyclohex-2-en-1-ylalane.
- Source :
-
Chemical Communications . 1/4/2017, Vol. 53 Issue 1, p111-114. 4p. - Publication Year :
- 2017
-
Abstract
- An efficient (+)-camphor-mediated kinetic resolution of racemic cyclohex-2-en-1-ylalane is described. This approach provides an enantiomerically enriched form of the alane, in situ available for synthetic uses. Applied to the allylation of aldehydes, this protocol leads to the corresponding homoallylalcohols in a highly enantioselective manner. [ABSTRACT FROM AUTHOR]
- Subjects :
- *KINETIC resolution
*ALLYLATION
*ALDEHYDES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 120317055
- Full Text :
- https://doi.org/10.1039/c6cc08649g