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A microporous Cd-MOF based on a hexavalent silicon-centred connector and luminescence sensing of small molecules.
- Source :
-
New Journal of Chemistry . 1/30/2017, Vol. 41 Issue 3, p1137-1141. 5p. - Publication Year :
- 2017
-
Abstract
- Solvothermal reaction of Cd2+ cations with a silicon-centered carboxylic acid (H6L) afforded a novel metal–organic framework, namely, [Cd3L(H2O)5]·DMA·H2O (1). It is built from three {CdO6} clusters and organosilicone linkers to form a 3D porous framework. The steric organosilicone ligand is among the never documented examples. Interestingly, 1 exhibited spontaneous formations of microtubular crystals, the phenomenon of which is rarely reported among the metal–organic coordination assemblies. In addition, the luminescence properties of 1 dispersed in different organic solvents have been investigated, displaying turn-on and turn-off luminescence responses for n-butanol and acetone, respectively. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CADMIUM compounds synthesis
*METAL-organic frameworks
*SILICON spectra
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 41
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 121025298
- Full Text :
- https://doi.org/10.1039/c6nj03470e