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2,6-Diisopropylanilinium Bromobismuthates.
- Source :
-
European Journal of Inorganic Chemistry . Jan2017, Vol. 2017 Issue 4, p798-804. 7p. 7 Diagrams, 3 Charts, 2 Graphs. - Publication Year :
- 2017
-
Abstract
- A systematic approach to obtain bromobismuthates with various bismuth/halide ratios stabilised by 2,6-diisopropylanilinium cations [ArNH3] (Ar = 2,6-diisopropylphenyl) is presented. New bromobismuthate compounds [(ArNH3)(BiBr4)]∞ (1), [(ArNH3)3(Bi2Br9)]∞ (2), [(ArNH3)3(BiBr6)] (3) and [(ArNH3)4(BiBr6)(Br)] (4) with Bi/Br ratios of 1:4, 1:4.5, 1:6 and 1:7 have been isolated and structurally characterised. [Bi2Br9]∞ is a new structural motif in halobismuthate chemistry. In all the compounds, extensive hydrogen bonding is observed between the bromobismuthate moiety and the 2,6-diiosopropylanilinium cation, thus stabilising the inorganic–organic hybrid structures. Preliminary optical spectroscopic studies indicate that the optical band gap can be tuned by controlling the bismuth/halide ratio, which results in different dimensionalities in the halobismuthate structure. The compounds exhibit thermal stability up to 250 °C. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BISMUTH compounds
*HALIDES
*CATIONS
*HYDROGEN bonding
*THERMAL stability
Subjects
Details
- Language :
- English
- ISSN :
- 14341948
- Volume :
- 2017
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- European Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 121046662
- Full Text :
- https://doi.org/10.1002/ejic.201601087