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Efficient synthesis of carborane azo derivatives and their reactivity.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 2/7/2017, Vol. 46 Issue 5, p1585-1592. 8p. - Publication Year :
- 2017
-
Abstract
- An iridium(iii)-catalyzed C–N-bond-forming direct synthesis of carborane azo derivatives was developed. The reaction of o-carborane monocarboxylate with aryldiazonium salt in the presence of a catalytic amount of [Cp*IrCl2]2 and NaOAc in CH3CN at 80 °C gave the corresponding carborane azo derivative in good yield. A series of cyclometalated iridium/rhodium complexes that contain Cp*M–B (M = Ir, Rh) bonds, and are stabilised by the intramolecular coordination of nitrogen donors, were successfully isolated and structurally characterised. [ABSTRACT FROM AUTHOR]
- Subjects :
- *IRIDIUM catalysts
*CHEMICAL bonds
*CARBORANES
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 46
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 121046993
- Full Text :
- https://doi.org/10.1039/c6dt04550b