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Selective B(4)−H Activation of an o-Carboranylthioamide Based on a Palladium Precursor.
- Source :
-
Chemistry - A European Journal . 2/3/2017, Vol. 23 Issue 8, p1814-1819. 6p. - Publication Year :
- 2017
-
Abstract
- Palladium(II)-induced selective B(4)−H activation of an o-carboranylthioamide has been developed. A tetranuclear palladium(II) complex has been obtained in high yield with excellent regioselectivity. DFT calculations have confirmed that the B(4)-borometalate is lower in energy than the corresponding B(3)-borometalate. The product proved to be a good precursor for target mononuclear or trinuclear B(4)−H activated complexes. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 23
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 121147437
- Full Text :
- https://doi.org/10.1002/chem.201603851