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Pure and strong red photoluminescence from Na0.5Gd0.5TiO3: Eu ferroelectric thin films under ultraviolet light excitation.
- Source :
-
Optical Materials . Feb2017, Vol. 64, p224-229. 6p. - Publication Year :
- 2017
-
Abstract
- A series of novel photoluminescent ferroelectric thin films Na 0.5 Gd 0.5 TiO 3 : x Eu (NGT: Eu) with various Eu 3+ doping concentrations were prepared at various heat-treated temperature, which have single pseudo-cubic perovskite structure at proper heat-treated temperature from 700 °C to 800 °C according to X-ray diffraction results. There existed narrow and intensive emission bands located at red light region ascribed to 5 D 0 → 7 F 2 and 5 D 0 → 7 F 1 transitions of Eu 3+ by 283 nm excitation. The strong energy absorption of NGT host and efficient energy transfer to Eu 3+ should be primarily responsible for the emissions. Gd 3+ acts as sensitizer which has an important role on the energy transfer from the host NGT to Eu 3+ . The luminescence from NGT: 0.25Eu thin films is the strongest for all the NGT: Eu films, and its color coordinate is (0.65, 0.32) close to ideal red light. The quenching concentration in NGT: Eu films reaches as high as 25%. The lifetime of emissive energy level Eu 3+ : 5 D 0 in NGT: 0.1Eu and NGT: 0.5Eu thin films is 1.024 ms and 0.931 ms, respectively. Finally, the ferroelectric property of NGT: 0.25Eu thin films was tested and the remanent polarization (2 P r ) is 7.10 μC/cm2 lower than that of Na 0.5 Bi 0.5 TiO 3 . [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09253467
- Volume :
- 64
- Database :
- Academic Search Index
- Journal :
- Optical Materials
- Publication Type :
- Academic Journal
- Accession number :
- 121174112
- Full Text :
- https://doi.org/10.1016/j.optmat.2016.12.022