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Diastereoselective Radical Oxidative C-H Aminations toward Chiral Atropoisomeric (P, N) Ligand Precursors.
- Source :
-
Organic Letters . Feb2017, Vol. 19 Issue 3, p600-603. 4p. - Publication Year :
- 2017
-
Abstract
- A new class of chiral atropoisomeric (P, N) ligand precursors has been obtained with excellent diastereoselectivities and high yields through diastereoselective metal-free intramolecular radical oxidative C-H amination with chiral phosphamide as the auxiliary group. This method provides a concise and highly valuable pathway for the synthesis of enantiopure aminophosphine ligands in large-scale. [ABSTRACT FROM AUTHOR]
- Subjects :
- *AMINATION
*PHOSPHINES
*PHOSPHORAMIDES
Subjects
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 19
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 121175708
- Full Text :
- https://doi.org/10.1021/acs.orglett.6b03625