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Highly Selective and Sensitive Colorimetric and Fluorescent Chemosensor for Rapid Detection of Ag, Cu and Hg Based on a Simple Schiff Base.
- Source :
-
Journal of Fluorescence . Mar2017, Vol. 27 Issue 2, p729-737. 9p. - Publication Year :
- 2017
-
Abstract
- A new reversible colorimetric and fluorescent chemosensor MMIP based on a simple Schiff base has been successfully synthesized. MMIP exhibited high selectivity and sensitivity towards Ag, Cu and Hg ions with a short response time in DMSO/HO (1/1, v/v) solution among various metal ions, and the results could be monitored directly by naked eyes. The binding stoichiometry between MMIP and Ag/Hg/Cu has been determined to be 1:2 by Job's plot and FT-IR analysis. MMIP could effectively detect Ag, Cu and Hg over a wide pH range of 3-10. The good linear correlations were obtained in the concentration ranges of 0-20 μM for Ag, Cu and Hg. Thus sensor MMIP could be potentially used for the quantification of Ag, Cu and Hg in aqueous solution. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10530509
- Volume :
- 27
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Journal of Fluorescence
- Publication Type :
- Academic Journal
- Accession number :
- 121484748
- Full Text :
- https://doi.org/10.1007/s10895-016-2005-y