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Disulfide-Directed C-H Hydroxylation for Synthesis of Sulfonyl Diphenyl Sulfides and 2-(Phenylthio)phenols with Oxygen as Oxidant.
- Source :
-
Advanced Synthesis & Catalysis . 3/6/2017, Vol. 359 Issue 5, p779-785. 7p. - Publication Year :
- 2017
-
Abstract
- Compared to N, O and P as directing functional atoms, the application of directing group containing sulfur atoms for transition metal-catalyzed C-H activation is much more difficult for the known reason (some metal catalysts are easily poisoned by sulfur). Here, the disulfide-directed C-H activation for thew synthesis of sulfonyl diphenyl sulfides was realized for the first time by a copper-catalyzed, tandem, one-step C-S coupling/hydroxylation of disulfides and arylboronic acids with oxygen as the oxidant. This method provides a mild and easy method for the synthesis of sulfonyl diphenyl sulfides and 2-(phenylthio)phenol derivatives and avoids producing sulfoxides and sulfones under air conditions and elevated temperatures. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METAL catalysts
*SULFUR
*CATALYSTS
*SULFIDES
*COPPER catalysts
*HYDROXYLATION
Subjects
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 359
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 121542616
- Full Text :
- https://doi.org/10.1002/adsc.201600861