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Rhodium-Catalyzed Enantioselective Isomerization of Secondary Allylic Alcohols.
- Source :
-
Journal of the American Chemical Society . 3/15/2017, Vol. 139 Issue 10, p3643-3646. 4p. - Publication Year :
- 2017
-
Abstract
- The first catalytic enantioselective isomerization of secondary allylic alcohols to access ketones with a α-tertiary stereocenter is presented. The racemic allylic alcohol substrates can be converted to the enantioenriched ketone products in a stereoconvergent fashion. The use of commercially available catalysts and mild reaction conditions makes this an attractive method in stereoselective synthesis. [ABSTRACT FROM AUTHOR]
- Subjects :
- *RHODIUM
*ISOMERIZATION
*KETOACIDOSIS
*ALLYL alcohol
*POLYMER aggregates
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 139
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 121922793
- Full Text :
- https://doi.org/10.1021/jacs.7b01096