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Magnesium Azotetrazole-1,1-dioxide: Synthesis and Promising Properties of Green Insensitive Energetic Materials.
- Source :
-
Zeitschrift für Anorganische und Allgemeine Chemie . 3/16/2017, Vol. 643 Issue 6, p432-436. 5p. - Publication Year :
- 2017
-
Abstract
- Magnesium azotetrazole-1,1'-dioxide (1) was first prepared and intensively characterized by single-crystal X-ray diffraction, IR spectroscopy, mass spectrometry, elemental analysis, and DSC measurements. The heat of formation was calculated using the atomization energy method based on quantum chemistry and the heat of detonation was also predicted. The NBO analysis was performed for inspecting charge distributions. The sensitivities towards impact and friction were tested using the BAM standard. The high detonation performance (5289 kJ·kg-1), good thermal stabilities (245.5 °C) and excellent insensitivity (39.2 J and >360 N) as well as clean decomposition products supports it of great interest as a promising candidate of green insensitive energetic materials. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00442313
- Volume :
- 643
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Zeitschrift für Anorganische und Allgemeine Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 121941621
- Full Text :
- https://doi.org/10.1002/zaac.201600471