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Ring-opening of cyclic ethers by aluminum hydridotriphenylborate.
- Source :
-
Chemical Communications . 3/25/2017, Vol. 53 Issue 24, p3493-3496. 4p. - Publication Year :
- 2017
-
Abstract
- Molecular aluminum hydride [(L)AlH2] (L = Me3TACD) reacted with 2 equiv. of BPh3 in THF or THP to give the cationic alkoxides [(L)Al(OR)][HBPh3] (R = nBu, nPent) by facile ring-opening of the cyclic ethers. The Cα–O bond cleavage which involves the isolable intermediate [(L)AlH][HBPh3] is a result of hydride transfer to Cα from [HBPh3]−. [ABSTRACT FROM AUTHOR]
- Subjects :
- *RING-opening reactions
*CYCLIC ethers
*ALUMINUM hydride
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 24
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 121970879
- Full Text :
- https://doi.org/10.1039/c7cc01159h