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Iterative C−H Functionalization Leading to Multiple Amidations of Anilides.
- Source :
-
Angewandte Chemie . 4/3/2017, Vol. 129 Issue 15, p4320-4324. 5p. - Publication Year :
- 2017
-
Abstract
- Polyaminobenzenes were synthesized by the ruthenium-catalyzed iterative C−H amidation of anilides using dioxazolones as an amino source. This strategy could be implemented by the sequential activation of C−H bonds of formerly generated compounds by cascade chelation assistance of newly installed amide groups. Computational studies provided a rationale. [ABSTRACT FROM AUTHOR]
- Subjects :
- *AMIDATION
*ANILIDES
*CARBON-hydrogen bonds
*CHELATION
*AMINO acids
Subjects
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 129
- Issue :
- 15
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 122100443
- Full Text :
- https://doi.org/10.1002/ange.201701138